New solid-state reactions of transition metal complexes
نویسندگان
چکیده
منابع مشابه
Solid-state electroluminescent devices based on transition metal complexes.
Transition metal complexes have emerged as promising candidates for applications in solid-state electroluminescent devices. These materials serve as multifunctional chromophores, into which electrons and holes can be injected, migrate and recombine to produce light emission. Their device characteristics are dominated by the presence of mobile ions that redistribute under an applied field and as...
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The group 6 metal mono-, bis- and tris-ferrocenylphosphine complexes [M(CO)5(PH2Fc)] (1a, M = Cr; 1b, M = Mo; 1c, M = W), cis-[M(CO)4(PH2Fc)2] (2a, M = Cr; 2b, M = Mo; 2c, M = W) and fac-[M(CO)3(PH2Fc)3] (3a, M = Cr; 3b, M = Mo; 3c, M = W) [Fc = Fe(η(5)-C5H4)(η(5)-C5H5)] were prepared and fully characterised. IR and NMR spectroscopy and single-crystal X-ray diffraction analysis indicate that Fc...
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Together with the transition metal carbides and borides, the transition metal nitrides belong to a family of materials that features an unusual combination of outstanding properties, among which are exceptional hardness, high melting point, metallic luster with sometimes vivid colors, and simple metallic structures combined with excellent electrical and thermal conductivities. This combination ...
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With the objective of elucidating the mechanisms of dioxygen activation by transition metal complexes, we have investigated functional models of some metalloenzymes, such as phenoxazinone synthase and catechol oxidase, based on bisdimethylglyoximatocobalt(II) and -iron(II) complexes. Kinetic studies and the identification of intermediates permitted to establish a free radical mechanism. The cat...
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A wide range of transition metal imido (TMI) complexes is studied using ab initio molecular orbital (MO) calculations. The main computational point of interest is the further testing of effective core potentials (ECPs) and valence basis sets to allow for the accurate calculation of properties for reasonably sized transition metal complexes. On the chemical side, several results from the study a...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 1981
ISSN: 0108-7673
DOI: 10.1107/s0108767381097146